Hydrogen production using mixed oxides: TiO2-M (CoO and WO3)

dc.contributor.authorPérez-Larios, Alejandro
dc.contributor.authorGómez, Ricardo
dc.date2013-12-01
dc.date.accessioned2019-03-19T16:23:01Z
dc.date.available2019-03-19T16:23:01Z
dc.descriptionIn this work we obtained materials of titanium dioxidewhit mixed oxide CoO-TiO2 and WO3-TiO2(1.0, 3.0, 5.0 %wt). The solids were characterizedby; nitrogen physisorption (BET) and porosity(BJH), XRD patterns and UV-Vis spectroscopy.The photoactivity was evaluated using a Pyrexreactor of 200 ml using a solution ethanol-water(1:1 molar ratio) and 0.1 g of catalyst using a highpressure Hg lamp (with a wavelength of 254 nmand an intensity of 2.2 mW/cm2 encapsulated ina quartz tube. The results showed materials withspecific surface area among 89 to 95 m2/g and 41to 91 m2/g with mesopority characteristics. TheXRD patterns show the formation of the crystallineanatase phase. The band gap energy (Eg) for thematerials were obtained with UV-Vis spectroscopy,the Eg values were lower than 3.2 eV for both mixedoxide. In the water splitting evaluation a maximin the efficient was found at Co and W at 5 wt.%.The hydrogen produced was 1000 μmol/h and 950μmol/h respectively, this is a value comparable torespect other works.en-US
dc.formatapplication/pdf
dc.identifierhttps://revistas.unilibre.edu.co/index.php/avances/article/view/2746
dc.identifier.urihttps://hdl.handle.net/10901/15239
dc.languagespa
dc.language.isospaspa
dc.publisherUniversidad Librees-ES
dc.relationhttps://revistas.unilibre.edu.co/index.php/avances/article/view/2746/2166
dc.relation.ispartofjournalRevistas – Ingenieríasspa
dc.rights.licenseAtribución-NoComercial-SinDerivadas 2.5 Colombia*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.5/co/*
dc.sourceAVANCES: Investigación en Ingeniería; Vol. 10 Núm. 2 (2013): Avances Investigación en Ingeniería; 27-34es-ES
dc.source2619-6581
dc.source1794-4953
dc.titleHydrogen production using mixed oxides: TiO2-M (CoO and WO3)en-US
dc.type.coarhttp://purl.org/coar/resource_type/c_6501
dc.type.coarversionhttp://purl.org/coar/version/c_970fb48d4fbd8a85

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